Product ID:51211, SUPER SHOCK-IT
MSDS Date:06/15/1998
FSC:6810
NIIN:01-358-4336
MSDS Number: CJVLS

Emergency Phone: 304-843-1300

Info Phone: 304-843-1300

Preparer: R. KENNETH LEE

Cage: 47695

Telephone: 1-800-245-2974 (CAL HYPO)

Cage: 47695

65% AVAILABLE CHLORINE)

CAS: 7778-54-3

RTECS: NH3485000

OSHA PEL 0.5 PPM (CL)

ACGIH TLV: 0.5PPM/1STEL(CL)9495

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

INERT INGREDIENTS (INCLUDES 5.5-10% MOISTURE)

LD50 LC50 Mixture:ORAL LD50 (RAT)= NOT SPECIFIED
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: LEAD TO IRRITATION OF
TISSUE & CAUSE VARIETY OF EFFECTS DEPENDENT ON CONC. UPPER RESP
TRACT IRRIT, NASAL CONGESTION, COUGH, SORE THROAT, LARYNGITIS,
SHORTNESS OF BREATH. IN OPERATIONS WHER E HI CONCENTRATION OF
RESPIRABLE PARTICULATES PULMONARY EDEMA MAY BE PRODUCED-IF NOT
TREATED IMMED CAN BE LIFE THREATENING, (SINCE PROD GRANULAR FORM
PARTICLES OF RESPIRABLE SIZE NOT GENERALLY ENCOUNT ERED). EYE/SKIN:
CORROSIVE TO EYES. SEVERE EYE IRRIT, EVEN BLINDNESS. SKIN-SEVERE
IRRITATION, BURNS, TISSUE DESTRUCTION. INGEST: SEVERE BURNS TO
DIGESTIVE TRACE, CAN BE FATAL.
Explanation of Carcinogenicity:PER MSDS: CALCIUM HYPOCHLORITE IS NOT
LISTED AS CARCINOGEN OR SUSPECTED CARCINOGEN BY NTP/IARC/OSHA.
Effects of Overexposure:INHALATION: IRRITATING TISSUE, UPPER
RESPERATORY TRACT IRRITATION, NASAL CONGESTION, COUGHING, SORE
THROAT, LARYNGITIS, SHORTNESS OF BREATH, PULMONARY EDEMA-CAN BE
LIFE THREATENING. CORROSIVE TO EYES, SEVERE EYE IRRITATION,
BLINDNESS. SEVERE SKIN IRRITATION, BURNS, TISSUE DESTRUCTION.
SEVERE BURNS TO DIGESTIVE TRACT & CAN BE FATAL IF INGESTED.
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:INHALATION: MOVE TO FRESH AIR.IF NOT BREATHING GIVE
ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING
DIFFICULT GIVE OXYGEN. CALL PHYSICIAN. EYE/SKIN CONTACT: IN CASE OF
CONTACT, IMMEDI ATELY FLUSH EYES AND SKIN WITH PLENTY OF WATER
(SOAP AND WATER FOR SKIN) FOR AT LEAST 15 MINUTES, WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. FOR EYE CONTACT, GET IMMEDIATE
MEDICAL ATTENTION. IF SKIN IRRITATION OCCURS, GET MEDICAL
ATTENTION. INGESTION: IF SWALLOWED, GIVE AT LEAST 3-4 GLASSES OF
WATER, BUT DO NOT INDUCE VOMITING. DO NOT GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS OR CONVULSING P ERSON. GET MEDICAL ATTENTION.

Flash Point:NONE
Extinguishing Media:WATER ONLY. SMOTHERING IS INEFFECTIVE AS PRODUCT
SUPPLIES ITS OWN OXYGEN.
Fire Fighting Procedures:PRODUCT DECOMPOSES AT 180 C RELEASING OXYGEN
GAS. CONTAINER MAY RUPTURE. FIRE-FIGHTERS MUST WEAR NIOSH
APPROVED, PRESSSURE, DEMAND, SELF-CONTAINED BREATHING APPARATUS
WITH FULL FACE PIECE FOR POSSIB LE EXPOSURE TO HAZARDOUS GASES.
Unusual Fire/Explosion Hazard:PRODUCT SUPPLIES ITS OWN OXYGEN.

Spill Release Procedures:USE EXTREME CAUTION IN HANDLING SPILLED
MATERIAL. CONTAMINATION WITH ORGANIC OR COMBUSTIBLE MATERIAL MAY
CAUSE FIRE OR VIOLENT DECOMPOSITION. IF FIRE OR DECOMPOSITION
OCCURS IN AREA OF SPILL, IMMEDIA TELY DOUSE WITH PLENTY OF WATER.
OTHERWISE, SWEEP UP ALL VISIBLE MATERIAL USING A CLEAN, DRY SHOVEL
AND BROOM AND DISSOLVE MATERIAL IN WATER. SPILLED MATERIAL THAT HAS
BEEN SWEPT UP AND DISSOLVED IN W
Neutralizing Agent:HYDROGEN PEROXIDE (1 PT OF 35% HYDROGEN PEROXIDE
SOLUTION PER POUND OF CALCIUM HYPOCHLORITE TO BE NEUTRALIZED).

Handling and Storage Precautions:STORE IN COOL DRY WELL VENTED AREA, IN
ORGINAL CONTAINER. KEEP CONTAINER CLOSED WHEN NOT IS USE. KEEP
AWAY FROM HEAT, SPARKS, FLAMES, DIRECT SUNLIGHT, AND OTHER SOURCES
OF HEAT, INCLUDING LIGHTED TOB ACCO PRODUCTS. USE ONLY A CLEAN,
DRY SCOOP MADE OF METAL OR PLASTIC EACH TIME PRODUCT IS TAKEN FROM
Other Precautions:FROM HANDLING/STG PRECAUTIONS: VIOLENT RX,FIRE/EXPLO.
FIRE MAY RESULT IF CONTAM W/ACIDS/EASILY COMBUST
MATL(OIL,KEROSENE,GASOLINE,PAINT,ORG MATL). DONT REUSE CNTNR.
RESIDUAL MATL REMAIN IN EMPTY DRM C AUSE FIRE.THOROUGHLY FLUSH
CNTNR W/H2O, DESTROY(PLACE IN TRASH COLLECTION). DONT CONTAM
H2O/FOOD/FEE D BY STORAGE/DISP.

Respiratory Protection:IF DUSTY CONDITIONS OCCUR OR ENCOUNTERED , USE
NIOSH APPROVED RESPIRATOR WITH ACID GAS CARTRIDGE & DUST
PRE-FILTER. THE RESPIRATORY USE LIMITATIONS MADE BY NIOSH OR THE
MANUFACTURER MUST BE OBSERVED. RESPIRATORY PROTECTION PROGRAMS
MUST BE IN ACCORDANCE WITH 29 CFR 1910.134.
Ventilation:NONE, UNLESS DUSTY CONDITIONS ARE ENCOUNTERED.
Protective Gloves:NATURAL OR SYNTHETIC RUBBER.
Eye Protection:CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:BOOTS, APRON OR CHEMICAL SUITS SHOULD BE
USED WHEN NECESSARY TO PREVENT SKIN CONTACT. PERSONAL PROTECTIVE
CLOTHING AND USE OF EQUIPMENT MUST BE IN ACCORDANCE WITH
29CFR1910.132, .133 & .138.
Work Hygienic Practices:SAFE HANDLING OF MATERIAL ON LONG-TERM BASIS
SHOULD EMPHASIZE MINIMIZING REPEATED ACUTE EXPOSURE.
Supplemental Safety and Health
FIRE MAY RESULT IF CONTAMINATED W/ACIDS OR EASILY COMBUSTIBLE MATERIAL
SUCH AS OIL, KEROSENE, GASOLINE, PAINT PRODUCTS & MOST ORGANIC
MATERIALS. DO NOT REUSE CONTAINER. THOROUGHLY FLUSH EMPTY CONTAINE
R W/WATER THEN DESTROY. DO NOT CONTAMINATE WATER, FOOD OR FEED BY
STORAGE OR DISPOSAL OF THIS PRODUCT.

HCC:D1
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:DECOMPOSES @180C
Decomp Temp:=180.C, 356.F
pH:ALKALINE
Solubility in Water:217 G/L @ 27 C.
Appearance and Odor:WHITE POWDER WITH SLIGHT CHLORINE ODOR.

Stability Indicator/Materials to Avoid:NO
CONTAMINATION. EXCESSIVE HEAT ABOVE 177 C, ACIDS, COMBUSTIBLE
MATERIALS, ORGANICS, REDUCING AGENTS.
Stability Condition to Avoid:UNSTABLE ABOVE 177 C.
Hazardous Decomposition Products:ACID OR AMMONIA CONTAMINATION WILL
RELEASE TOXIC GASES. EXCESSIVE HEAT WILL CAUSE DECOMPOSITION
RESULTING IN THE RELEASE OF OXYGEN AND CHLORINE GAS.

Waste Disposal Methods:SPILLED MATERIAL THAT HAS BEEN SWEPT UP AND
DISSOLVED IN WATER SHOULD BE USED IMMEDIATELY IN THENORMAL
APPLICATION FOR WHICH THIS PRODUCT IS BEING USED. IF THIS IS NOT
POSSIBLE, CAREFULLY NEURALIZE D ISSPLVED MATERIAL BY ADDING
HYDROGEN PEROXIDE(ONE PINT OF 35% HYDROGEN PEROXIDE SOLUTION PER
POUND O F CALCIUM HYPOCHLORITE TO BE NEUTRALIZED)

Toxicological Information:ACUTE INHALATION LC50: RAT - NO MORTALITY AT
3.5 MG/L (1 HR), IRRITATING. ACUTE DERMAL LD50: RABBIT >1000 MG/KG,
SLIGHT TO VERY LOW TOXICITY. SKIN IRRITATION: CAUSES BURNS. EYE
IRRITATION: CAUSES BURN S. ACUTE ORAL LD50: RAT - 850 MG/KG. SLIGHT
TO VERY LOW TOXICITY. CHRONIC EFFECTS/CARCINOGINITY: PRODUCT IS NOT
LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN BY NTP, IARC, OR
OSHA.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:HIGHLY TOXIC TO AQUATIC LIFE. 0.088 MG/L (BLUEGILL) 96-HOUR
LC50.

Transport Information:SEE TRANSPORTATION SECTION.

SARA Title III Information:SARA 311/312 HAZARD CLASS: ACUTE HEALTH
HAZARD, REACTIVE HAZARD, FIRE HAZARD. SARA 313: NOT LISTED. SARA
302: NOT LISTED AS AN EXTREMELY HAZARDOUS SUBSTANCE.
Federal Regulatory Information:LISTED ON TSCA INVENTORY. LISTED ON
EUROPEAN EINECS. LISTED ON CANADIAN DSL. LISTED ON AUSTRALIAN ECL.
LISTED ON JAPAN MITI. LISTED ON TABLE 302.4 OF 40CFR PART 302 AS
HAZARDOUS SUBSTANCE WITH RQ OF 10 LBS. REPORT RELEASES TO AIR,
LAND, WATER IN EXCESS OF RQ TO NATIONAL RESPONSE CENTER AT
800-424-8802. NFPA RATING: HEALTH - 3, FLAMMABILITY - 0, REACTIVITY
- 1 (OXIDIZER). FIFRA: REGISTERED AS A PE STICIDE.
State Regulatory Information:NOT PROVIDED